You can force assign a candidate to a job from Step 5 of the Create New Job wizard :

On Step 5 of the Create New Job wizard, select Assign Job to a Candidate option.

On the Candidate Name box, type the candidate’s name and select it. It will inform you that the candidate is Not available. Click Confirm.

Then you can click Submit. 

Note: When you force assign candidates in spite of their availability, ensure that they are auto-confirmed since they would not be able to accept the assignment due to the same availability factor.

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